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Alkyl groups have an electron-donating character, ... (2.52 versus 2.20 on the Pauling scale), meaning that an alkyl group should theoretically withdraw electrons from its adjacent atom.
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Chemists find alkyl groups are electron-withdrawing, challenging a century-old belief - MSNScientists are calling for changes to chemistry textbooks after discovering a fundamental aspect of structural organic chemistry has been incorrectly described for almost 100 years.
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